Syntheses of lignin-derived thioacidolysis monomers and their uses as quantitation standards.
Identifieur interne : 002900 ( Main/Exploration ); précédent : 002899; suivant : 002901Syntheses of lignin-derived thioacidolysis monomers and their uses as quantitation standards.
Auteurs : Fengxia Yue [République populaire de Chine] ; Fachuang Lu ; Run-Cang Sun ; John RalphSource :
- Journal of agricultural and food chemistry [ 1520-5118 ] ; 2012.
Descripteurs français
- KwdFr :
- MESH :
- composition chimique : Glycérol, Lignine.
- Acide chlorhydrique, Chromatographie en phase gazeuse, Chromatographie gazeuse-spectrométrie de masse, Ionisation de flamme, Thiols.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Glycerol, Lignin.
- Chromatography, Gas, Flame Ionization, Gas Chromatography-Mass Spectrometry, Hydrochloric Acid, Sulfhydryl Compounds.
Abstract
Analytical thioacidolysis releases diagnostic monomers from lignins by selectively cleaving alkyl aryl ether bonds. High yielding syntheses of the three thioacidolysis monomers were developed, and the compounds were used as standards for gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detector (GC-FID) quantitation of monomers released from lignocellulosics. First, syringyl, guaiacyl, and p-hydroxyphenyl glycerols were synthesized from the corresponding ethyl cinnamates and used as thioacidolysis substrates to prepare the monomers in high yields. These monomers were then used as standard compounds to measure their GC-MS and GC-FID response factors against two internal standards, 4,4'-ethylenebisphenol and tetracosane. For quantitation, it was shown that 4,4'-ethylenebisphenol is the better internal standard for GC-MS, whereas tetracosane remains the choice for GC-FID. When the obtained response factors were applied, the thioacidolysis monomer yields from white spruce, loblolly pine, poplar, bamboo, and sugar cane bagasse were determined by GC-MS. The obtained results were consistent with those reported in the literature.
DOI: 10.1021/jf204481x
PubMed: 22191493
Affiliations:
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Syntheses of lignin-derived thioacidolysis monomers and their uses as quantitation standards.</title><author><name sortKey="Yue, Fengxia" sort="Yue, Fengxia" uniqKey="Yue F" first="Fengxia" last="Yue">Fengxia Yue</name><affiliation wicri:level="3"><nlm:affiliation>State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, People's Republic of China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou</wicri:regionArea><placeName><settlement type="city">Jiangmen</settlement><region type="province">Guangdong</region></placeName></affiliation></author><author><name sortKey="Lu, Fachuang" sort="Lu, Fachuang" uniqKey="Lu F" first="Fachuang" last="Lu">Fachuang Lu</name></author><author><name sortKey="Sun, Run Cang" sort="Sun, Run Cang" uniqKey="Sun R" first="Run-Cang" last="Sun">Run-Cang Sun</name></author><author><name sortKey="Ralph, John" sort="Ralph, John" uniqKey="Ralph J" first="John" last="Ralph">John Ralph</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2012">2012</date><idno type="RBID">pubmed:22191493</idno><idno type="pmid">22191493</idno><idno type="doi">10.1021/jf204481x</idno><idno type="wicri:Area/Main/Corpus">002B97</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Corpus" wicri:corpus="PubMed">002B97</idno><idno type="wicri:Area/Main/Curation">002B97</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Curation">002B97</idno><idno type="wicri:Area/Main/Exploration">002B97</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Syntheses of lignin-derived thioacidolysis monomers and their uses as quantitation standards.</title><author><name sortKey="Yue, Fengxia" sort="Yue, Fengxia" uniqKey="Yue F" first="Fengxia" last="Yue">Fengxia Yue</name><affiliation wicri:level="3"><nlm:affiliation>State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, People's Republic of China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou</wicri:regionArea><placeName><settlement type="city">Jiangmen</settlement><region type="province">Guangdong</region></placeName></affiliation></author><author><name sortKey="Lu, Fachuang" sort="Lu, Fachuang" uniqKey="Lu F" first="Fachuang" last="Lu">Fachuang Lu</name></author><author><name sortKey="Sun, Run Cang" sort="Sun, Run Cang" uniqKey="Sun R" first="Run-Cang" last="Sun">Run-Cang Sun</name></author><author><name sortKey="Ralph, John" sort="Ralph, John" uniqKey="Ralph J" first="John" last="Ralph">John Ralph</name></author></analytic><series><title level="j">Journal of agricultural and food chemistry</title><idno type="eISSN">1520-5118</idno><imprint><date when="2012" type="published">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chromatography, Gas (MeSH)</term><term>Flame Ionization (MeSH)</term><term>Gas Chromatography-Mass Spectrometry (MeSH)</term><term>Glycerol (chemistry)</term><term>Hydrochloric Acid (MeSH)</term><term>Lignin (chemistry)</term><term>Sulfhydryl Compounds (MeSH)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Acide chlorhydrique (MeSH)</term><term>Chromatographie en phase gazeuse (MeSH)</term><term>Chromatographie gazeuse-spectrométrie de masse (MeSH)</term><term>Glycérol (composition chimique)</term><term>Ionisation de flamme (MeSH)</term><term>Lignine (composition chimique)</term><term>Thiols (MeSH)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Glycerol</term><term>Lignin</term></keywords><keywords scheme="MESH" qualifier="composition chimique" xml:lang="fr"><term>Glycérol</term><term>Lignine</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Chromatography, Gas</term><term>Flame Ionization</term><term>Gas Chromatography-Mass Spectrometry</term><term>Hydrochloric Acid</term><term>Sulfhydryl Compounds</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Acide chlorhydrique</term><term>Chromatographie en phase gazeuse</term><term>Chromatographie gazeuse-spectrométrie de masse</term><term>Ionisation de flamme</term><term>Thiols</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Analytical thioacidolysis releases diagnostic monomers from lignins by selectively cleaving alkyl aryl ether bonds. High yielding syntheses of the three thioacidolysis monomers were developed, and the compounds were used as standards for gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detector (GC-FID) quantitation of monomers released from lignocellulosics. First, syringyl, guaiacyl, and p-hydroxyphenyl glycerols were synthesized from the corresponding ethyl cinnamates and used as thioacidolysis substrates to prepare the monomers in high yields. These monomers were then used as standard compounds to measure their GC-MS and GC-FID response factors against two internal standards, 4,4'-ethylenebisphenol and tetracosane. For quantitation, it was shown that 4,4'-ethylenebisphenol is the better internal standard for GC-MS, whereas tetracosane remains the choice for GC-FID. When the obtained response factors were applied, the thioacidolysis monomer yields from white spruce, loblolly pine, poplar, bamboo, and sugar cane bagasse were determined by GC-MS. The obtained results were consistent with those reported in the literature.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">22191493</PMID><DateCompleted><Year>2012</Year><Month>04</Month><Day>19</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1520-5118</ISSN><JournalIssue CitedMedium="Internet"><Volume>60</Volume><Issue>4</Issue><PubDate><Year>2012</Year><Month>Feb</Month><Day>01</Day></PubDate></JournalIssue><Title>Journal of agricultural and food chemistry</Title><ISOAbbreviation>J Agric Food Chem</ISOAbbreviation></Journal><ArticleTitle>Syntheses of lignin-derived thioacidolysis monomers and their uses as quantitation standards.</ArticleTitle><Pagination><MedlinePgn>922-8</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/jf204481x</ELocationID><Abstract><AbstractText>Analytical thioacidolysis releases diagnostic monomers from lignins by selectively cleaving alkyl aryl ether bonds. High yielding syntheses of the three thioacidolysis monomers were developed, and the compounds were used as standards for gas chromatography-mass spectrometry (GC-MS) and gas chromatography-flame ionization detector (GC-FID) quantitation of monomers released from lignocellulosics. First, syringyl, guaiacyl, and p-hydroxyphenyl glycerols were synthesized from the corresponding ethyl cinnamates and used as thioacidolysis substrates to prepare the monomers in high yields. These monomers were then used as standard compounds to measure their GC-MS and GC-FID response factors against two internal standards, 4,4'-ethylenebisphenol and tetracosane. For quantitation, it was shown that 4,4'-ethylenebisphenol is the better internal standard for GC-MS, whereas tetracosane remains the choice for GC-FID. When the obtained response factors were applied, the thioacidolysis monomer yields from white spruce, loblolly pine, poplar, bamboo, and sugar cane bagasse were determined by GC-MS. The obtained results were consistent with those reported in the literature.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Yue</LastName><ForeName>Fengxia</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, People's Republic of China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Lu</LastName><ForeName>Fachuang</ForeName><Initials>F</Initials></Author><Author ValidYN="Y"><LastName>Sun</LastName><ForeName>Run-Cang</ForeName><Initials>RC</Initials></Author><Author ValidYN="Y"><LastName>Ralph</LastName><ForeName>John</ForeName><Initials>J</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType><PublicationType UI="D013486">Research Support, U.S. Gov't, Non-P.H.S.</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>01</Month><Day>19</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Agric Food Chem</MedlineTA><NlmUniqueID>0374755</NlmUniqueID><ISSNLinking>0021-8561</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D013438">Sulfhydryl Compounds</NameOfSubstance></Chemical><Chemical><RegistryNumber>11132-73-3</RegistryNumber><NameOfSubstance UI="C036909">lignocellulose</NameOfSubstance></Chemical><Chemical><RegistryNumber>9005-53-2</RegistryNumber><NameOfSubstance UI="D008031">Lignin</NameOfSubstance></Chemical><Chemical><RegistryNumber>PDC6A3C0OX</RegistryNumber><NameOfSubstance UI="D005990">Glycerol</NameOfSubstance></Chemical><Chemical><RegistryNumber>QTT17582CB</RegistryNumber><NameOfSubstance UI="D006851">Hydrochloric Acid</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D002849" MajorTopicYN="N">Chromatography, Gas</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D005410" MajorTopicYN="N">Flame Ionization</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008401" MajorTopicYN="N">Gas Chromatography-Mass Spectrometry</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D005990" MajorTopicYN="N">Glycerol</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D006851" MajorTopicYN="N">Hydrochloric Acid</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008031" MajorTopicYN="N">Lignin</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D013438" MajorTopicYN="N">Sulfhydryl Compounds</DescriptorName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2011</Year><Month>12</Month><Day>24</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2011</Year><Month>12</Month><Day>24</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2012</Year><Month>4</Month><Day>20</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">22191493</ArticleId><ArticleId IdType="doi">10.1021/jf204481x</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>République populaire de Chine</li></country><region><li>Guangdong</li></region><settlement><li>Jiangmen</li></settlement></list><tree><noCountry><name sortKey="Lu, Fachuang" sort="Lu, Fachuang" uniqKey="Lu F" first="Fachuang" last="Lu">Fachuang Lu</name><name sortKey="Ralph, John" sort="Ralph, John" uniqKey="Ralph J" first="John" last="Ralph">John Ralph</name><name sortKey="Sun, Run Cang" sort="Sun, Run Cang" uniqKey="Sun R" first="Run-Cang" last="Sun">Run-Cang Sun</name></noCountry><country name="République populaire de Chine"><region name="Guangdong"><name sortKey="Yue, Fengxia" sort="Yue, Fengxia" uniqKey="Yue F" first="Fengxia" last="Yue">Fengxia Yue</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Bois/explor/PoplarV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002900 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 002900 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Bois
|area= PoplarV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:22191493
|texte= Syntheses of lignin-derived thioacidolysis monomers and their uses as quantitation standards.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:22191493" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a PoplarV1
| This area was generated with Dilib version V0.6.37. |  |